Omzeilen van het sandelin-effect: Onderzoek naar de lasbaarheid van een laag siliciumhoudende lasdraad (ZINQWeld)

Senne
Moortgat
  • Debby
    Van den Eynde

Omzeilen van het sandelin-effectOnderzoek naar de lasbaarheid van een laag siliciumhoudende lasdraad (ZINQWeld) Hot dip galvanized welded steel structures, when made of sensitive steels, often show abnormalities inthe coating layer, particularly on the weld surface. The aspect of the coating layer, with an increasedthickness over the welds in comparison with the normal layer, shows a dull grey look and isaesthetically less appealing. This is known as the sandelin-effect. The scope of this master thesis aimsto avoid this phenomenon by investigating the weldability of a low silicon consumable (ZINQWeld)for the MAG-welding process.The problem originates from the increased silicon content in the weld metal used, due to the highersilicon content in the consumable in comparison with the base material. If the Silicon level is withinspecific ranges, the sandelin-effect will occur.Tests show that the problem disappears when a welding consumable with low Silicon content(ZINQWeld) is used. For ZINQWeld the Silicion content is 0.14%, compared to a standard weldingwire with 0.7% and unfortunately yielding an increased viscosity and a higher risk of porosities in theweld metal. To reduce these secondary problems, the influence of the welding parameters, thecomposition of the shielding gas and the welding power source used have been studied. A visualevaluation shows that each shielding gas and type of power source used has its own scope. In otherwords, there isn’t an optimal over all combination of shielding gas and power source to be chosen thatproduces satisfactory results for each weld shape and material thickness. However, an acceptable levelof quality is achieved with ZINQWeld according to ISO 5817.This study shows that in a dilution range between approximately 10 to 50% a satisfactory zinc coatingthickness is found with ZINQWeld. This implicates that the increase in thickness of the zinc layer onthe weld is not excessive and that the layer meets the minimum thickness according to ISO 1461.When no increased growth in coating thickness occurs, it is assumed that there is a good adhesionbetween the zinc layer and the base material.Two welding wires with identical chemical composition are used. Using the 1.2 mm ZINQWeldwelding wire, experiments show no clear qualitative preference for the shielding gas. The 1.0 mmwelding wire on the other hand, only yields a good result when using the shielding gas Arcal 12.Despite the welding wires identical chemical composition, it can be argued that the 1.2 mm weldingwire shows a better weldability.The main conclusion of this study is that the ZINQWeld consumable provides a solution related to theSandelin-effect for any future welding application in comparison with a standard welding wire. This isdemonstrated with different Preliminary Welding Procedures Specifications (pWPSs) that are drawnup based on test pieces from customers. Keywords: Galvanizing, Sandelin-effect, ZINQWeld, Silicon

Bibliografie

Referentielijst1. ALCO. Oppervlaktebehandeling voor metalen: Elektrolytisch verzinken. [cited 20135 oktober]; Available from: http://www.alcobvba.be/alco/aanbod/elektrolytischverzinken.shtml.2. Galvaniseren. 2005 [cited 2014 10 februari]; Available from:http://nl.wikipedia.org/wiki/Galvaniseren.3. Weert-Groep. Verzinken en poedercoaten. 2013 [cited 2013 17 november]; Availablefrom: http://www.weertgroep.be/nl-nl/1/61/thermisch-verzinken.aspx.4. Clusta. Thermisch verzinken. Fiche Nr. 5 - juli 1997 [cited 2014 8 maart]; Availablefrom: http://www.bmt.nl/groepen/000/000-011/000-011-010.5. Sapart, C., Presentatie: duroZINQ verzinken. 2013, Galva Power.6. AGA (American Galvanizers Association), Design Guide-The Design of Products tobe Hot-Dip Galvansized after Fabrication. 2010, American Galvanizers Assocation.7. IBBT. Thermisch verzinken. 2012 [cited 2013 17 november]; Available from:http://ibbt.emis.vito.be/node/42655.8. AGA (American Galvanizers Association), Design Guide-The Design of Products tobe Hot-Dip Galvansized after Fabrication. 2000, American Galvanizers Association.9. Graepel. Thermisch verzinken tegen corrosie. [cited 2014 12 februari];Available from:http://www.graepel.de/nl/producten/andere-producten-en-verzinkerij/verz…. GalvaPower. Wat is thermisch verzinken? [cited 2013 24 november]; Available from:http://www.galvapower.com/nl/toepassingen/proces-thermisch-verzinken.as…. Joskin. Galvanisatie. 2014 [cited 2014 12 februari]; Available from:http://www.joskin.com/?page=galvanisation&user_lang=nl.12. HDGASA (Hot Dip Galvanizers Association Southern Africa). The reactions betweeniron & zinc. [cited 2013 13 november]; Available from:http://www.ckit.co.za/secure/conveyor/troughed/corrosion-protection/ste…. Marder, A.R., The metallurgy of zinc-coated steel. Progress in Materials Science,2000. vol. 45: p. 191-271.14. Reumont, G., P. Perrot, and J. Foct, Thermodynamic study of the galvanizing processin a Zn–0.1%Ni bath. Journal of Materials Science, 1998. vol. 33(19): p. 4759-4768.15. Kozdras, M.S. and P. Niessen, Silicon-induced destabilization of galvanized coatingsin the sandelin peak region. Metallography, 1989. vol. 22: p. 253-267.16. Sapart, C., E-mail: Toepassingsdomein ZINQWeld. 2014, Galva Power.17. Foct, J., G. Reumont, and P. Perrot, Interpretation of the role of silicon on thegalvanizing reaction based on kinetics, morphology and thermodynamics. ScriptaMetallurgica et Materialia, 1993. vol. 28: p. 1195-1200.18. Foct, J., et al., How does silicon lead the kinetics of the galvanizing reaction to lose itssolid-solid character. Journal De Physique IV, 1993. vol. 3(C7): p. 961-966.19. Bicao, P., et al., Effects of zinc bath temperature on the coatings of hot-dipgalvanizing. Surface and Coatings Technology, 2008. vol. 202(9): p. 1785-1788.20. Watson, K.B., et al., Welding consumables for galvanizing kettles. AustralasianWelding Journal, 2001. vol. 46: p. 33-47.21. Zinkinfo-Benelux. Thermisch verzinken. [cited 2014 12 februari]; Available from:http://zinkinfobenelux.com/nl.8822. Thielco-Staalindustrie. Doordacht construeren. [cited 2014 12 februari]; Availablefrom: http://www.thielco.nl/_download/doordacht%20construeren.pdf.23. ITW-welding. MIG/MAG lassen. [cited 2014 5 maart]; Available from:http://www.itw-welding.com/media/Pdf/Las%20advies/QSmigd.pdf.24. FME-CWM, vm 124: MIG/MAG lassen en zijn varianten. 2008.25. Essers, W.G. and F. Neessen, MIG/MAG en gevulde draad lassen, in InternationalWelding Engineer: Lasprocessen en apparatuur. 2011 Nederlands Instituut voorLastechniek.26. Van Beek, B. Lassen van staalconstructies. [cited 2013 20 november]; Availablefrom: http://www.cybercomm.nl/~cesmetel/kennisweb/lassen/las0_1.htm.27. Prinsen, J. and A. Gales, Stroombronnen voor het booglassen, in InternationalWelding Engineer: Lasprocessen en apparatuur. 2011, Nederlands Instituut voorLastechniek.28. Avesta-Welding. Solid wires for all methods. 2012 [cited 2014 13 februari]; Availablefrom: http://www.midwaymetals.com.au/wp-content/uploads/2012/02/WELDINGWIRE.p…. Essers, W.G., De elektrische boog, in International Welding Engineer: Lasprocessenen apparatuur. 2011, Nederlands Instituut voor Lastechniek.30. Air-Liquide. L'encyclopédie des Gaz. 2013 [cited 2014 4 februari]; Available from:http://encyclopedia.airliquide.com/encyclopedia.asp.31. Essers, W.G. and T. Luijendijk, TIG lassen, in International Welding Engineer:Lasprocessen en apparatuur. 2011, Nederlands Instituut voor Lastechniek.32. Kumar, V., et al. CRA Weld Overlay - Influence of welding process and parameters ondilution and corrosion resistance. 2010 [cited 2013 14 november]; Available from:http://www.twi-global.com/technical-knowledge/published-papers/cra-weld…. Yang, J.L., S.R. Chandel, and J.M. Bibby. The effects of process variables on the welddeposit area of submerged arc welds. 1993 [cited 2013 14 november]; Availablefrom: http://www.aws.org/wj/supplement/WJ_1993_01_s11.pdfhttp://www.aws.org/w…. Aghakhani, M., E. Mehrdad, and E. Hayati, Parametric Optimization of Gas MetalArc Welding Process by Taguchi Method on Weld Dilution. International Journal ofModeling and Optimization, 2011. vol. 1(3): p. 216-220.35. Murugan, N. and R.S. Parmar, Effects of MIG process parameters on the geometry ofthe bead in the automatic surfacing of stainless steel. Journal of Materials ProcessingTechnology, 1994. vol. 41(4): p. 381-398.36. Pors, W., Beschermende lagen, in International Welding Engineer: Materiaalkunde.2011, Nederlands Instituut voor Lastechniek.37. Shahi, A.S. and S. Pandey, Modelling of the effects of welding conditions on dilutionof stainless steel claddings produced by gas metal arc welding procedures. Journal ofMaterials Processing Technology, 2008. vol. 196(1–3): p. 339-344.38. Karadeniz, E., U. Ozsarac, and C. Yildiz, The effect of process parameters onpenetration in gas metal arc welding processes. Materials & Design, 2007. vol. 28(2):p. 649-656.39. Kim, I.S., et al., A study on relationship between process variables and beadpenetration for robotic CO2 arc welding. Journal of Materials Processing Technology,2003. vol. 136(1–3): p. 139-145.8940. Kannan, T. and J. Yoganandh, Effect of process parameters on clad bead geometryand its shape relationships of stainless steel claddings deposited by GMAW. TheInternational Journal of Advanced Manufacturing Technology, 2010. vol. 47(9-12): p.1083-1095.41. Yang, L.J., R.S. Chandel, and M.J. Bibby, The effects of process variables on the beadwidth of submerged-arc weld deposits. Journal of Materials Processing Technology,1992. vol. 29(1–3): p. 133-144.42. Air-Liquide, Arcal 14 MAG-lassen van koolstofstaal.43. Suban, M. and J. Tušek, Dependence of melting rate in MIG/MAG welding on the typeof shielding gas used. Journal of Materials Processing Technology, 2001. vol. 119(1–3): p. 185-192.44. Tus̆ek, J. and M. Suban, Experimental research of the effect of hydrogen in argon as ashielding gas in arc welding of high-alloy stainless steel. International Journal ofHydrogen Energy, 2000. vol. 25(4): p. 369-376.45. Brak, C.A., Structuur van de lasverbinding, in International Welding Engineer:Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.46. Brak, C.A., Legeringen en fasediagrammen, binaire legeringen, in InternationalWelding Engineer: Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.47. Brak, C.A., Ijzer-koolstoflegeringen, in International Welding Engineer:Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.48. Brak, C.A., Ongelegeerde C en C-Mn staalsoorten, in International WeldingEngineer: Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.49. Bekkers, K., Fijnkorrelstaalsoorten, in International Welding Engineer:Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.50. Varnauskas, V., V. Rudzinskas, and O. Černašėjus, Influence of covering componentsof welding electrodes on chemical composition and mechanical properties of fusedmetal. 2004: Materials science.51. Anya, C. and T. Baker, The Effect of Silicon on the Grain Size and the TensileProperties of Low Carbon Steels. 1989: Materials Science and Engineering. p. 197-206.52. CAl, M., et al., Transformation Behavior of Low Carbon SteelsContaining.TwoDifferent Si Contents. 2009: Journal of Iron and Steel Research. p. 55-60.53. Brak, C.A., Scheuren in lasverbindingen, in International Welding Engineer:Materiaalkunde. 2011, Nederlands Instituut voor Lastechniek.54. Neessen, F., Booglassen met beklede elektroden, in International Welding Engineer:Lasprocessen en apparatuur. 2011, Nederlands Instituut voor Lastechniek.55. NIL. Laskennis opgefrist nr. 59: Lasbaarheid van materialen - staal. 2009 [cited2014 12 februari]; Available from:http://www.nil.nl/public/cms/lists/upload/59_staal.pdf.56. ESAB. Carbon & Low Alloy Steel Filler Metals for the GMAW, GTAW and SAWWelding Processes. 2000 [cited 2014 13 februari]; Available from:http://www.esabonline.com/EUWeb/AWTC/Lesson6_9.htm.57. Anya, C., Higher silicon to manganese ratios in low carbon structural steels. 1991:Journal of material science letters. p. 562-564.58. Ben nasr, J., et al., Optimization of hot-dip galvanizing process of reactive steels:Minimizing zinc consumption without alloy additions. Materials Letters, 2008. vol.62(19): p. 3328-3330.59. De Abreu, Y., et al., Study of zinc coatings on steel substrate attained by two differenttechniques. Surface and Coatings Technology, 1999. vol. 120–121(0): p. 682-686.9060. ZINQ and G. Power. microZINQ Minder is Meer. 2014 [cited 2014 4 februari];Available from: http://www.zinq.com/nl/thermisch-verzinken/microzinqr/Availablefrom: http://www.galvapower.com/nl/MICROZINQ.aspx.61. Pinger, T. and C. Sapart, Presentatie: Eigenschappen microZINQ 5 en vergelijkingmet het klassiek discontinu thermisch verzinken. 2013, Fontaine Technologie.62. Weert-Groep. Deltacoat. 2014 [cited 2014 8 april]; Available from:http://www.galvaco.be/nl-nl/1/100/deltacoat.aspx.63. Matz, C., Method For Arc Welding With Consumable Electrode, L. AG, Editor. 2010,LINDE AG64. Garcia de Lucas, C., Presentation: Review of European Markets in 2007. 2008,EGGA: Copenhagen.65. EGGA (European General Galvanizers Association). Presentatie: Duurzaam bouwenmet thermisch verzinken. [cited 2014 12 februari]; Available from:http://www.infosteel.be/staalbouwdag10/brunoDursin_NL.pdf.66. Altrad-Benelux. Mefran steigers. [cited 2014 12 februari]; Available from:http://altrad-benelux.be/nl/products/mefran-steigers/mefran-steigers/mu…. van Eijnsbergen, J.F.H. and J. Bakker. Maxpro. 2000 [cited 2013 15 december];Available from: http://www.mecolin.nl/maxpro.html.68. Eendengarage. Gegalvaniseerd chassis. 2010 [cited 2014 12 februari]; Availablefrom: http://www.eendengarage.com/chassisvergroting1.htm.69. Francken-Metaal. Verzinkerij. [cited 2014 12 februari]; Available from:http://www.franckenmetaal.nl/index.php/verzinkerij/.70. Air-Liquide. MIG lassen. 2011 [cited 2014 16 februari]; Available from:http://www.airliquide.be/nl/toepassingen-gassen/lassen-snijbranden-ther…. Elcometer. Elcometer 456. 2013 [cited 2014 8 april]; Available from:http://www.elcometer.com/nl/component/productmanager/productmanager?pro…. Petzow, G., Metallographic Etching. 2 ed. 1999, Materials Park, Ohio: AmericanSociety for Metals.73. van den Berg, R., Kwaliteitsborging en kwaliteitscontrole, in International WeldingEngineer: Fabricage en toepassingen. 2011, Nederlands Instituut voor Lastechniek.74. BCSA, Corus, and SCI. Steel Industry Guidance Notes SN 46: Welding ProcedureSpecifications (WPSs). 2010 [cited 2014 2 mei]; Available from:http://www.steelconstruction.org/resources/guidance-notes.html.

Download scriptie (4.78 MB)
Universiteit of Hogeschool
KU Leuven
Thesis jaar
2014